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Wednesday, June 26, 2013
Questions on Atomic Physics Including JEE (Advanced) 2013 Questions
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Monday, April 20, 2009
AIEEE 2008- An Imaginary Question on Bohr Model
The following question was included in the AIEEE 2008 question paper:
Suppose an electron is attracted towards the origin by a force k/r where ‘k’ is a constant and ‘r’ is the distance of the electron from the origin. By applying Bohr’s model to this system, the radius of the nth orbital of the system is found to be ‘rn’ and the kinetic energy of the electron to be ‘Tn’. Then which of the following is true?
(1) Tn α 1/n2, rn α n2
(2) Tn independent of n, rn α n
(3) Tn α 1/n, rn α n
(4) Tn α 1/n, rn α n2
The force k/r supplies the centripetal force for the circular motion of the electron so that we have
k/r = mv2/r where ‘m’ is the mass and ‘v’ is the speed of the electron.
Therefore, mv2 = k which is
Also, v = √(k/m).
The angular momentum of the electron in the nth orbit of radius rn is mvrn and in the Bohr model mvrn = nh/2π where ‘h’ is Planck’s constant. Substituting for ‘v’ we have
m×√(k/m) ×rn = nh/2π
This gives rn α n. So the correct option is (2).
In the above question the attractive force on the electron was imagined to be inversely proportional to the distance just for the sake of testing your problem solving skill. In a real hydrogen atom the force is certainly inversely proportional to the
Tuesday, May 27, 2008
IIT-JEE 2008: Linked Comprehension Type Multiple Choice Questions on Bohr Model of Hydrogen-like Atoms
Monday, March 10, 2008
Two Questions (MCQ) on Bohr Atom Model
You can find the earlier questions (with solution) on Bohr atom model posted on this site by clicking on the label ‘Bohr model’ or ‘hydrogen atom’ below this post. You can get them also by using the search option at the top of this page. Today I give you two questions which are meant for gauging the depth of your understanding of Bohr’s theory.
(1) When the electron in a hydrogen atom of mass M undergoes transition from an orbit of higher quantum number n2 to an orbit of lower quantum number n1, the recoil velocity acquired by the atom is (Rydberg’s constant = R, Planck’s constant = h)
(a) (R/hM) (1/n12 – 1/n22)
(b) (hR/M) (n2 – n1)
(c) 1/hRM (1/n12 – 1/n22)
(d) h/RM) (1/n12 – 1/n22)
(e) (hR/M) (1/n12 – 1/n22)
The wave number of the photon emitted because of the electron transition is
ν' = 1/λ = R(1/n12 – 1/n22) where λ is the wave length of the photon and R is Rydberg’s constant.
The momentum of the photon is p = h/λ = hR(1/n12 – 1/n22) where h is Planck’s constant.
When the photon is emitted with this momentum, the atom recoils (like a gun firing a bullet) with an equal and opposite momentum. Therefore, the recoil velocity of the atom is given by
v = p/M = (hR/M)(1/n12 – 1/n22).
(2) If the radius of the innermost electron orbit in a hydrogen atom is R1, the de Broglie wave length of the electron in the second excited state is
(a) πR1
(b) 3πR1
(c) 4πR1
(d) 6πR1
(e) 9πR1
The wave length of the electron in the nth orbit is given by
λ = 2πRn/n where Rn is the radius of the nth orbit.4
[This follows because the angular momentum of the electron in the nth orbit is
mvRn = nh/2π.
Therefore, de Broglie wave length, λ = h/mv = 2πRn/n ]
The second excited state has quantum number n = 3 (Third orbit). The radius of the 3rd orbit in terms of the radius R1 of the first orbit is given by (remembering Rn = n2 R1)
R3 = 9R1
Therefore, λ = 2πRn/n = 2π×9R1/3 = 6πR1
[It will be convenient to remember that the de Broglie wave length of the electron in the nth orbit is n times the the wave length in the innermost orbit].
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